Dichlorido[N′-(3,5-dichloro-2-hydroxybenzylidene)pyridine-4-carbohydrazide-κN](1,10-phenanthroline-κ2 N,N′)cobalt(II) methanol monosolvate
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چکیده
In the title compound, [CoCl(2)(C(13)H(9)Cl(2)N(3)O(2))(2)(C(12)H(8)N(2))]·CH(3)OH, the Co(II) atom is octahedrally coordinated by two N atoms from the pyridyl rings of the tridentate N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide (H(2)L) ligand, two N atoms from the 1,10-phenanthroline ligand and two chloride ions. The acyl-hydrazone groups are not involved into the coordination of the metal ion. In the crystal packing an extended three-dimensional network formed by N-H⋯Cl, N-H⋯O, O-H⋯N, O-H⋯N and O-H⋯Cl hydrogen bonds is observed.
منابع مشابه
Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)-1,10-phenanthroline-κ2 N,N′]cadmium(II)
The asymmetric unit of the title compound, [CdCl(2)(C(17)H(14)N(4))], contains two independent mol-ecules in which the Cd(II) ions are in distorted trigonal-bipyramidal CdN(3)Cl(2) coordination environments. In the crystal structure, there is a π-π stacking inter-action involving a pyridine ring and a symmetry-related benzene ring, with a centroid-centroid distance of 3.5088 (19) Å.
متن کاملmer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ3 S,N 1,O)(methanol-κO)(1,10-phenanthroline-κ2 N,N′)nickel(II)
In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octa-hedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thio-semicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N-H⋯Cl, N-H⋯N, C-H⋯S and O-H⋯S hydrogen bonds.
متن کاملDichlorido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)cobalt(II)
In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are disordered about the mirror plane and areeach half-occupied. In the crystal structure, π-π inter-act...
متن کامل[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN 2)-1,10-phenanthroline-κ2 N,N′]bis(thiocyanato-κN)cadmium(II)
In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π-π stacking inter-action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid-centroid distance of 3.578 (3) Å.
متن کاملcis-Bis[(4-nitrophenyl)cyanamido-κN 1]bis(1,10-phenanthroline-κ2 N,N′)nickel(II) methanol monosolvate
In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa-hedral geometry and is chelated by two phenanthroline ligands and two phenyl-cyanamide groups which occupy cis positions. The (4-nitro-phen-yl)cyanamide anions act as monodentate ligands. There is one classical inter-molecular O-H⋯N hydrogen bond and several C-...
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